Home 4.5 Metallic bonding
4.5 Metallic bonding
Metallic Bonding
- Metals have low ionization energies, so valence electrons can be delocalized throughout metal.
- Structure of metal is a giant lattice of positive ions (cations) surrounded by “sea” of delocalized electrons
- Metallic Bond: the electrostatic attraction between a lattice of positive ions (cations) and delocalized electrons
- Strength of metallic bond depends on
- Number of valence electrons that can become delocalized
- The charge of the metal ion
- The ionic radius of the metallic positive ion (cation)
Alloys
- Alloy is a mixture that consists either of
- Two or more metals
- Metal(s) combined with an alloying element (one or more non-metals)
- Alloys have enhanced properties such as strength, hardness and durability
Electrical Conductivity
- Metals are good conductors because the delocalized electrons can move through the metallic structure and carry a current
- Presence of impurities can restrict movement
Malleability
- Metals are malleable because cations can slide past each other which leads to rearrangement of solid (Non-directional bonding)
Trends in melting points
- Melting point depends on the strength of the attractive forces that hold the delocalized electron together